I like to count the days post LH (surge). So, if she was about 2.0 on Monday, then Tues. is day 1 - post LH. Then breed on days 3 & 5 or 4 & 6 post LH. (This would be assuming that she reached 5.0 with no problem). If I was trying to figure the days of ovualation, I would do the same. If she was about 5.0 on Wed, then Thurs is day 1 after ovulation. If you know what time (approx) she was 5.0 - I suppose you could count the hours from 5.0. As - 5.0 on Wed 7AM - then 48 hours after ovulation would be Friday AM. (approx)
Ovulation day is day 0. So if your girl ovulates on Sunday and you want to breed on day 2 and day 4, you would breed on Tuesday and Thursday.
Good Luck